https://www.aibang.com/a/48710

殊化學(xué)品公司朗盛和德國(guó)海拉胡克集團(tuán)公司合作開(kāi)發(fā)了一種名為Pocan AF4130的新型復(fù)合材料,用作電池管理單元(BMU)和兩個(gè)單元監(jiān)控單元(CMU)的外殼材料。

聚對(duì)苯二甲酸丁二醇酯(PBT)和丙烯酸酯-苯乙烯-丙烯腈(ASA)的共混物含有30%(按重量計(jì)算)的玻璃纖維和鹵素阻燃劑包。該材料的特殊優(yōu)點(diǎn)是其極低的翹曲和收縮,加上其高阻燃性。Lanxess高性能材料(HPM)業(yè)務(wù)部門的銷售總監(jiān)Marc Marbach表示:“我們認(rèn)為這種材料在汽車電池系統(tǒng)精密零部件的應(yīng)用潛力很大。”從最初的想法到廣泛的測(cè)試,再到可以用于全面的生產(chǎn),只用了兩年半的時(shí)間。

海拉為德國(guó)汽車電池制造商生產(chǎn)BMU和CMU。目前這種非常平坦的設(shè)備正在德國(guó)小型車的鋰離子電池系統(tǒng)中使用。

朗盛為電動(dòng)汽車的電池組件推出新的PBT復(fù)合材料

圖 海拉為德國(guó)汽車電池制造商生產(chǎn)BMU和CMU

偏差低

BMU和CMU的外殼具有大的平坦表面以及具有復(fù)雜幾何形狀的邊緣和內(nèi)部。由于其創(chuàng)新的設(shè)計(jì),BMU和CMU的外殼可以成本有效地作為單一組件注塑成型。當(dāng)外殼安裝在印刷電路板上時(shí),連接器的接觸端不能混在一起。因此,連接器支架與插腳的切口之間的間距公差是非常接近的?!斑@正是我們的混合物Pocan AF4130出色的尺寸穩(wěn)定性所在。”Marbach解釋說(shuō)。

UL 94 5VA和UL f1

該材料在美國(guó)測(cè)試機(jī)構(gòu)保險(xiǎn)商實(shí)驗(yàn)室公司的UL94防火測(cè)試中獲得了V-0(0.75毫米)的最佳阻燃等級(jí)。UL黃卡上也顯示該材料UL94防火等級(jí)為5VA(1.5mm)。

該材料用于阻燃外殼部件的注射成型。另外UL f1數(shù)據(jù)顯示,該材料還可用于涉及暴露于UV光線和水的戶外應(yīng)用中。Marbach補(bǔ)充說(shuō):“我們的復(fù)合材料也可用于光伏插頭和插座之類的電氣部件上?!?/span>

低揮發(fā)性和可容許范圍內(nèi)的排放量

Lanxess根據(jù)VDA 278標(biāo)準(zhǔn)(德國(guó)汽車工業(yè)協(xié)會(huì))進(jìn)行的熱解吸分析所證明的,這種材料表面由熱塑性塑料制作成型,排放非常低。“因此,它也適用于需要非常低揮發(fā)性和可容許范圍內(nèi)排放的許多汽車應(yīng)用,例如汽車內(nèi)飾部?!盡arbach表示。

對(duì)常見(jiàn)電池電解質(zhì)有良好的抵抗性

該混合物對(duì)機(jī)動(dòng)車輛中使用的典型介質(zhì)(如燃料,油,清潔劑和汽車護(hù)理產(chǎn)品)具有很強(qiáng)的抵抗能力,這在Lanxess為海拉胡克進(jìn)行的廣泛的介質(zhì)儲(chǔ)存測(cè)試中得到證實(shí),符合供應(yīng)規(guī)范LV 124,這一被許多汽車制造商認(rèn)定的標(biāo)準(zhǔn)。該材料還顯示出對(duì)廣泛用于鋰離子電池的電解質(zhì)的良好抗性,對(duì)此也按DIN EN22088-3進(jìn)行了負(fù)載測(cè)試?!皹悠芳词乖?,000小時(shí)的曝光后也沒(méi)有明顯的裂縫,還可以使用?!盡arbach表示。

綜合性的HiAnt服務(wù)

Lanxess在研發(fā)外殼組件方面為海拉胡克提供了額外的支持。這些服務(wù)是HiAnt客戶服務(wù)包的一部分。例如,HPM提供了優(yōu)化組件設(shè)計(jì)的建議,提供所有外殼組件電腦輔助設(shè)計(jì)是需要的材料性能數(shù)據(jù)以滿足預(yù)期負(fù)載并進(jìn)行模流分析,幫助進(jìn)行起初的注塑成型試驗(yàn)。這家特種化學(xué)品公司進(jìn)一步通過(guò)離子色譜法為Hella確定了混合物中鹵化物含量,并對(duì)VDA 270進(jìn)行了氣味測(cè)試。


LANXESS launches new PBT compound for battery components in electric cars

Specialty chemicals company LANXESS has developed a new  compound called Pocan AF4130 in collaboration with HELLA KGaA Hueck &  Co., based in Lippstadt, Germany. It serves as a housing material for a  battery management unit (BMU) and two cell monitoring units (CMU).

The blend of polybutylene terephthalate (PBT) and  acrylic ester-styrene-acrylonitrile (ASA) contains 30 percent by weight glass  fibers and a halogen-based flame retardance package. “The particular  advantages of the material are its extremely low warpage and shrinkage,  combined with its high flame retardance. We see great potential for  application in precision components for vehicle battery systems,” says Marc  Marbach, head of Sales Segments E&E in the LANXESS High Performance  Materials (HPM) business unit. It took just two-and-a-half years to go from  the initial idea to extensive testing and finally to use in full-scale production.  

HELLA fabricates the BMU and CMUs for a German  manufacturer of battery systems for motor vehicles. The very flat devices  currently are used in the lithium-ion battery system of a German compact car.  

Low tolerances

The housings of the BMU and CMUs have large, flat  surfaces as well as complex geometries along the edges and on the inside.  Thanks to their innovative design, they can be injection molded  cost-effectively as single components. The contact pins for the connectors  must not bend when the housings are mounted on the printed circuit boards.  The tolerances for the spacing between the connector mounts and the cut-outs  for the pins are therefore extremely close. “This is precisely where the  outstanding dimensional stability of our blend Pocan AF4130 pays off,”  explains Marbach.

UL 94 5VA- and UL f1-listed

As required for this application, the material achieves  the best classification of V-0 (0.75 millimeters) in UL 94 fire testing by  the U.S. testing organization Underwriters Laboratories Inc. It further is  listed on the UL Yellow Card with a good classification of UL 94 5VA (1.5  millimeters). The material is destined for the injection molding of  flame-retardant housing components. It additionally has been given a UL f1  listing for use in outdoor applications involving exposure to UV light and  water. “Our compound thus has a good chance of also being used for electrical  components such as photovoltaic plugs and sockets,” says Marbach.

Low volatile and condensable emissions

Surfaces made of this thermoplastic are very  low-emission, as demonstrated by thermal desorption analyses conducted by  LANXESS in accordance with VDA 278 (German Association of the Automotive  Industry). “It is therefore also suitable for many motor vehicle applications  requiring very low volatile and condensable emissions, such as components for  the automotive interior,” says Marbach.

Good resistance to common battery electrolytes

The blend is highly resistant to typical media used in  motor vehicles, such as fuels, oils, cleansers and car care products, as  proven in extensive media storage tests conducted by LANXESS for HELLA in  accordance with the supply specification LV 124, used by many automotive  manufacturers. It also displays good resistance to an electrolyte widely used  in lithium-ion batteries. The corresponding test was additionally conducted  under load in compliance with DIN EN 22088-3. “No cracks were evident in the  samples even after 1,000 hours of exposure,” explains Marbach.

Comprehensive HiAnt services

LANXESS provided HELLA with extensive support in  developing the housing components. These services are part of its HiAnt  customer service package. For example, HPM delivered suggestions for optimal  component design, provided all the characteristic material data required for  the computer-aided design of the housing parts to meet expected loads and for  the mold flow analyses, and supported the initial injection molding trials.  The specialty chemicals company further determined the blend’s halogenide  content for HELLA by means of ion chromatography and conducted odor testing  to VDA 270.

英文信息來(lái)源:https://lanxess.com/,艾邦高分子編輯整理。

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